oppenauer oxidation sentence in Hindi
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- The Oppenauer oxidation is still used for the oxidation of acid labile substrates.
- The Oppenauer oxidation is also used to synthesize hormones.
- Progesterone is prepared by the Oppenauer oxidation of pregnenolone.
- An advantage of the Oppenauer oxidation is its use of relatively inexpensive and non-toxic reagents.
- The Oppenauer oxidation is also used in the synthesis of lactones from 1, 4 and 1, 5 diols.
- This method, however, has the ability to undergo the reverse Oppenauer oxidation due to the proximity of the two reagents.
- The Oppenauer oxidation is commonly used in various industrial processes such as the synthesis of steroids, hormones, alkaloids, terpenes, etc.
- Chiral resolution of this racemic compound with digitonin produced chiral "'28 "'and on Oppenauer oxidation chiral "'29 " '.
- Oxidation of primary alcohols to form aldehydes can be achieved under milder, chromium-free conditions by employing methods or reagents such as IBX acid, Dess Martin periodinane, Swern oxidation, TEMPO, or the Oppenauer oxidation.
- Another advantage of the Oppenauer oxidation which makes it unique to other oxidation methods such as pyridinium chlorochromate ( PCC ) and Dess Martin periodinane is that secondary alcohols are oxidized much faster than primary alcohols, thus chemoselectivity can be achieved.
- Firstly, the double bond in ring D is hydrogenated, followed by Oppenauer oxidation of the hydroxyl group and the concurrent migration of the remaining olefin from ring B to ring A so that it is in conjugation with the ketone carbonyl group at position 3.
- The A value is a thermodynamic parameter and was originally measured along with other methods using the Gibbs free energy equation and, for example, the Meerwein Ponndorf Verley reduction / Oppenauer oxidation equilibrium for the measurement of axial versus equatorial values of cyclohexanone / cyclohexanol ( 0.7kcal / mol ).
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